Section 1 - Chemical Product and Company Identification



Products Name:                                                     Gum Rosin

Company                                                                  Rolfes Chemicals

                               A Division of Rolfes Group of Companies

                               Cnr Brammer and Strachan, Industries East

                               Germiston

Information (Product safety)                               Telephone: +27 11 873 0157 Fax: +27 11 8738480

Emergency telephone                                         South Africa +27 (0)86 044 44 11

 

 

 

Section 2 - Composition, Information on Ingredients



 

CAS#



Chemical Name:



%



EINECS#



8050-09-7



Rosin



100%



232-475-7



Hazard Symbols:                                                   Xi

Risk Phrases:                                                         R 43

 

Section 3 - Hazards Identification



           EMERGENCY OVERVIEW

This product is not classified as hazardous according to Directive 67/548/EEC

           Potential Health Effects

Eye:                                 Concentrated solutions may cause mild irritation.

Skin:                                  May cause skin irritation. Heated product may cause burns on contact. In case of contact with                                                        molten rosin, do not attempt to remove from skin. Cool for at least 15 minutes under running                                                                    water and seek medical attention.

Ingestion:                              May cause irritation of the digestive tract if a large amount is ingested.

Inhalation:                              Not applicable at ambient temperature. May cause respiratory tract irritation if powder is inhaled.

Chronic:                                 Not available

 

Chemical Hazards

When exposed to air, powdered rosin may oxidize. Oxidized rosin is a skin sensitizer. When over-heated, fumes may be formed, which may cause asthmatic attacks.    

 

 

Section 4 - First Aid Measures



           Eyes:                                                             Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the                                                                                                 upper and lower eyelids. Get medical aid.

Skin:                                                                Get medical aid. Flush skin with plenty of water for at least 15 minutes while                                                                                                   removing contaminated clothing and shoes.

           Ingestion:                                                            Get medical aid. Do not induce vomiting. Rinse mouth out with water but do not                                                                                                       drink.

          Inhalation:                                                            Remove from exposure and move to fresh air immediately. If not breathing, give                                                                                          artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

           Notes to Physician:                                 Treat symptomatically and supportively.

 

Section 5 - Fire Fighting Measures



General Information:                                          As in any fire, wear a self-contained breathing apparatus in pressure-demand,                                             MSHA/NIOSH (approved or equivalent), and full protective gear.

Extinguishing Media:                             Use dry chemical, carbon dioxide, or chemical foam. Water jet will scatter the                                       product.

Hazardous Decomposition/                               Can form flammable or explosive mixtures when finely divided dust is suspended in

Combustion Products:                                       the air.

 

Section 6 - Accidental Release Measures



           General Information:                                          Use proper personal protective equipment as indicated in Section 8.

Environmental                                            Should not be released into the environment. Prevent further leakage or

Precautions:                                                           spillage if safe to do so.

Methods for cleaning up:                        Sweep up material and dispose of as hazardous waste.

 

Section 7 - Handling and Storage



Handling:                                                                No special precautions required but avoid skin and eye contact. Prevent formation of mist. Eye and skin contact should be avoided if working at elevated temperatures.

Storage:                                                                  Store in a cool, dry place. Store in a well ventilated area. Keep fumes and dust to a minimum, in particular avoid formation of rosin dust.

Other Recommendations:                                Avoid contact with strong oxidizing agents.

 

Section 8 - Exposure Controls, Personal Protection



Engineering Controls:                                        Facilities storing or utilizing this material should be equipped with an eyewash                                                                                             facility and a safety shower. Use adequate ventilation to keep airborne                                                                                                            concentrations low.

Exposure Limits                                                   CAS# 8050-09-7: WEL (EH40UK2002) as nuisance dust

                                                                                    Total inhalable dust              10 mg/m3             Long term (8Hrs TWA)

                                                                                    Respirable dust                       4 mg/m3               Long term (8Hrs TWA)

 

Personal Protective Equipment

           Eyes:                                                             Wear tightly sealed chemical safety goggles.

           Skin:                                                              Wear appropriate protective gloves to prevent skin exposure.

           Clothing:                                            Wear appropriate protective clothing to prevent skin exposure.

           Respirators:                                               Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European                                                                                          Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved                                                                                           respirator if exposure limits are exceeded or if irritation or other symptoms are                                                                                              experienced.

 

Section 9 - Physical and Chemical Properties



 

Physical State:



Solid



 



Color:



Amber translucent



 



Odor:



Slight odor



 



pH:



Not applicable



 



Vapor Pressure:



0.00 mmHg @ 25°C



 



Viscosity:



Not applicable



 



Softening Point:



70-80°C @ 760mmHg



 



Melting Point:



Approx. 260°C



 



Autoignition Temperature:



Approx. 400°C



 



Flash Point:



Approx. 180°C (Pensky Martens)



 



Explosion Limits: Lower:



N/A



 



Explosion Limits: Upper:



N/A



 



Decomposition Temperature:



>280°C



 



Solubility in water:



Insoluble



 



Specific Gravity/Density:



1065-1077 kg/m3



 



Molecular Formula:



Not applicable



 



Molecular Weight:



Not applicable

 



 



 



Section 10 - Stability and Reactivity













 

Chemical Stability:



Stable under normal temperatures and pressures. Fine particles will oxidize slowly when exposed to air.



Conditions to Avoid:



Extreme heat. Keep away from sources of ignition and naked flames.



Incompatibilities with

Other Materials:



Strong oxidizing agents.



Hazardous Decomposition

Products:



In fire, emits oxides of carbon and acrid smoke. Under certain conditions organic acids, aldehydes and terpenes may be liberated. When over-heated fumes will be emitted which may cause asthmatic attacks when inhaled.



Hazardous Polymerization:



Will not occur.





 

 

Section 11 - Toxicological Information



 

RTECS#:



CAS# 8050-09-7



LD50/LC50:



Oral 7600 mg/kg (rat)



Inhalation:



Excessive inhalation of dust, or fumes when heating, may cause bronchial irritation. Noxious and irritating fumes may be given off upon over-heating. Over 400°C vapours may give rise to products which could cause asthmatic attacks.



Skin:



Caution. When exposed to air, powdered rosin may oxidize. Oxidized rosin is a skin sensitizer. Short term contact may cause irritation. Prolonged or repeated contact may cause sensitization insusceptible individuals.



Eyes:



May be irritating to eyes by mechanical abrasion.



Ingestion:



Unlikely to cause internal irritation if ingested.



Other:



See actual entry in RTECS for complete information.





 

Section 12 - Ecological Information



           Ecotoxicity:

           - Fish                               96h LC50: 1 mg/l

           - Algae                            48h EC50: 10 mg/l

           - Bacteria                       72h LC50: 100 mg/l

 

           Mobility:                         Low potential for absorption into soil.

          

           Persistence and        Readily biodegradable (OECD 301).

           Degradability:

          

Section 13 - Disposal Considerations



           Dispose of in a manner consistent with federal, state, and local regulations.

 

Section 14 - Transport Information



 

 



IATA



IMO



RID/ADR



SHIPPING NAME



Not regulated.



Not regulated.



Not regulated.



HAZARD CLASS



Not regulated.



Not regulated



Not regulated



UN NO.



Not regulated.



Not regulated



Not regulated



PACKING GROUP



Not regulated.



Not regulated



Not regulated



 

Section 15 - Regulatory Information



 

European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols:                                       Xi

Risk Phrases:                                            R 43           May cause sensitization by skin contact

Safety Phrases:                                         S 2              Keep out of reach of children

                                                                          S 24             Avoid contact with skin

                                                                          S 37             Wear suitable gloves

 

WGK (Water Danger/Protection) :       CAS# 232-475-7: 1 Low hazard to water

Canada:                                                      CAS# 232-475-7 is listed on Canada's DSL List

 

US Federal:

TSCA :                                                           CAS# 232-475-7 is listed on the TSCA Inventory.

 

 

 

 

Section 16 - Other Information



 

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damage